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In order to wash clothes with water containing dissolved calcium hydrogen carbonate, which cleaning agent will you prefer and why : soaps or synthetic

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In order to wash clothes with water containing dissolved calcium hydrogen carbonate, which cleaning agent will you prefer and why : soaps or synthetic detergents ?
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Disadvantage of using detergents. Soaps are biodegradable while detergents having branched hydrocarbon chains are not biodegradable and hence cause water pollution in rivers and other waterways.
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