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What is compressibility factor (Z)?

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Compressibility factor (Z): 

i. It is defined as the ratio of product PV and nRT.

z = \(\frac{PV}{nRT}\)

ii. Deviation from ideal behaviour is measured in terms of compressibility factor.

iii. For ideal gases, Z = 1 under all conditions of temperature and pressure. Therefore, the graph of Z versus P will be a straight line parallel to pressure axis. 

iv. For gases that deviate from ideal behaviour, value of Z deviates from unity. Note: Variation of compressibility factor for some gases

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