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Alkanes are considered as Paraffins. So, they undergo substitution reactions but not addition reactions. Explain with suitable example.

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CH4 + Cl2 \(\overset{Sunlight}{\underset{}{\longrightarrow}}\) CH3Cl + HCl

CH3Cl + Cl2 \(\overset{Sunlight}{\underset{}{\longrightarrow}}\) CH2Cl2 + HCl

CH2Cl2 + Cl2 \(\overset{Sunlight}{\underset{}{\longrightarrow}}\) CHCl3 + HCl

CHCl3 + Cl2 \(\overset{Sunlight}{\underset{}{\longrightarrow}}\) CCl4 + HCl

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