Correct option is (a) Anode is made of pure metal while cathode is made of impure metal
During copper metal refining by electrolytic method.
following reactions take places--
At Anode- oxidation take place-
Cu(s) → Cu+2(aq) + 2e-
At anode Cu oxidized to Cu+2 and come into electrolyte.
At cathode- (Reduction take place)
Cu+2(aq) + 2e- → Cu(s)
At cathode - Cu is deposited.
There, Anode is made of Impure cupper and cathode is made of pure copper.