Correct option is (d) gaseous volumes
In the reaction, N2 + 3H2 → 2NH3, the ratio by volume of N2, H2 and NH3 is 1:3:2. This illustrates the law of Gaseous volumes or Gay Lussac's law of combining volumes of gases.
According to this law, when gases react together to produce gaseous products, the volume of reactants and products bear a simple whole-number ratio with each other, provided volumes are measured at the same temperature and pressure.