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Polytropic Process.

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During actual expansion and compression processes of gases, pressure and volume are often related by (PVn = ), where n and C are constants. A process of this kind is called a polytropic process. The (P-V) diagram for such a process is shown below.

 As mentioned, the general equation for polytropic processes is expressed as: 

PVn = C

From the above equation, we can derive the following equations in the same method as in adiabatic processes:

From Eq. (1), the work done is derived in the same method earlier and expressed as:

The heat transfer for polytropic processes does not equal zero and can be calculated from the following equation:

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