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The number of unpaired electrons in liquid oxygen molecule is

(A) 1

(B) 2

(C) 3

(D) 4

1 Answer

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Best answer

Correct option is (B) 2

Oxygen molecule (\(O_2\)): Each oxygen atom has 8 electrons. Hence, \(O_2\) molecule has a total of 16 electrons. The electronic configuration of \(O_2\) molecule therefore is:

\(O_2:(\sigma1s)^2(\sigma*1s)^2(\sigma2s)^2(\sigma∗2s)^2(\sigma2p_z)^2(\pi2p_x)^2=(\pi2p_y)^2(\pi∗2p_x)^1=(\pi∗2p_y)^1\)

As we can see from the above electronic configuration, there are two unpaired electrons in the antibonding molecular \(\pi\)-orbital which leads to oxygen exhibiting paramagnetic properties.

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