Pyrolusite is MnO2 used to prepare KMnO4 . Steps are, MnO2 + I → I MnO42- + II → MnO4- .
Steps I and II are respectively :
(A) fuse with KOH / air and electrolytic oxidation.
(B) fuse with KOH / KNO3 and electrolytic oxidation.
(C) fuse with conc. HNO3 / air and electrolytic reduction.
(D) dissolve in H2O and oxidation.