The surface of a colloidal particle adsorbs one type of ion due to preferential adsorption. This Stem layer layer attracts the oppositely charged ions in the. medium and hence the boundary separating the Slpping plane two electrical double layers are set up. This is called Helmholtz electrical double layer. As the particles nearby are having similar charges. they cannot come close and condense. Hence this helps to explain the stability of the colloid.
