Join PS
Now, ∠POR = 2 ∠PQR (∠ at the center in twice the ∠ at the remaining circumference)
∠SOQ = 2 ∠SRQ (∠ at the center is twice the ∠ at the remaining circumference)
But ∠PQR = ∠SRQ (Alternate ∠s, PQ || RS)
∴ ∠POR = ∠SOQ
⇒ Arc PR = Arc QS (In the same circle, arcs subtending equal angles at the center are equal.) Hence, proved.
[Note. It is clear otherwise also.]
∵ PQR = SRQ
∴arc PR = arc QS.